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原子結構--元素王國法則(未完成)

Aug 03, 2008 陳 tinper3

參考文獻:觀念化學第2冊,化學元素王國之旅

Cool:It's SHOW TIME ~

在1904年日本物理學家Hantaro Nagaoka提出電子以固定軌道繞著原子核運轉的原子模型.

後來到了20世紀量子學說出現,提出了更合適的原子模型來描述原子構造. 但因為我還不是很了解量子學說有關粒子結合波的性質這些概念,所以在此就先掠過. 就直接切入由量子學說發展出來的原子模型論吧!

原子核外的電子並沒有依循固定軌道運轉, 到目前為止,我們可以利用量子力學算出電子在核外任何地方可能出現的機率. 我們稱這種描述電子出現機率的區域為"原子軌域". 而且,在越接近原子核的地方電子出現的機率就越高. 現在,讓我們來談談有關能量與軌域之間的事情吧!

我們都知道,質子和電子會相互吸引,互相束縛著. 所以,如果電子要逃脫原子核的魔掌,它就必須擁有更高的能量才能擺脫束縛. 在繼續說明之前必須先穿插個小觀念: "某物體是量子化的"這句話是什麼意思? 舉例來說,鉛筆心蕊的質量是由許許多多個碳原子的質量所組成的;一個物體所帶的電荷是由許多單一電子所帶電荷組成的,我們說質量及電荷都是量子化的,因為質量及電荷這種概念都是由基本單元一直累加形成.( 就好比2的倍數這種概念就符合量子化的定義, Ex:2的倍數一定是這樣的形式:2+2+2+.....<2就是單位元>)      好,現在回歸主題. 科學家已經知道電子的能量是量子化的(我很想知道原因,使實驗發現?or推理結果?)   所以這就表示:電子在吸收能量後所占有的軌域也是量子化的. 也就是說,電子必須吸收一定量的能量(電子的能量單位元),才能脫離束縛,進而佔有某個特定大小的軌域.

說完能量和軌域之間的關係後,接下來就要詳細說明軌域的種類及個別的特性及影響囉~!Innocent

 

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